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\u7f29\u5199AOTF\uff09\u6280\u672f\u7684\u95ee\u4e16\uff0c\u88ab\u8ba4\u4e3a\u662f\u201c90\u5e74\u4ee3\u8fd1\u7ea2\u5916\u5149\u8c31\u4eea<\/a>\u6700\u7a81\u51fa\u7684\u8fdb\u5c55\u201d[2]<\/sup>\u3002AOTF\u662f\u4e00\u79cd\u5efa\u7acb\u5728\u5149\u5b66\u5404\u5411\u5f02\u6027\u4ecb\u8d28\u7684\u58f0\u5149\u884d\u5c04\u539f\u7406\u4e0a\u7684\u7535\u8c03\u8c10\u6ee4\u6ce2\u5668[3~5]<\/sup>\uff0c\u4e0e\u901a\u5e38\u7684\u5355\u8272\u5668\u76f8\u6bd4\uff0c\u91c7\u7528\u58f0\u5149\u8c03\u5236\u5373\u901a\u8fc7\u8d85\u58f0\u5c04\u9891\u7684\u53d8\u5316\u5b9e\u73b0\u5149\u8c31\u626b\u63cf\uff0c\u5149\u5b66\u7cfb\u7edf\u65e0\u79fb\u52a8\u6027\u90e8\u4ef6\uff0c\u6ce2\u957f\u5207\u6362\u5feb\u3001\u91cd\u73b0\u6027\u597d\uff0c\u7a0b\u5e8f\u5316\u7684\u6ce2\u957f\u63a7\u5236\u4f7f\u5f97\u8fd9\u79cd\u4eea\u5668\u7684\u5e94\u7528\u5177\u6709\u66f4\u5927\u7684\u7075\u6d3b\u6027\u3002\u58f0\u5149\u53ef\u8c03\u6ee4\u5149\u5668\u8fd1\u7ea2\u5916<\/a>\u5149\u8c31\u4eea<\/a>\u5668\u7684\u8fd9\u4e9b\u4f18\u70b9\u4f7f\u5176\u8fd1\u5e74\u6765\u5728\u5de5\u4e1a\u5728\u7ebf\u548c\u73b0\u573a\uff08\u5ba4\u5916\uff09\u5206\u6790\u4e2d\u5f97\u5230\u8d8a\u6765\u8d8a\u5e7f\u6cdb\u7684\u5e94\u7528[6,7]<\/sup>\u3002\u76ee\u524d\u56fd\u5185\u4e5f\u6709\u76f8\u5173\u7684\u7814\u7a76\u5728\u8fdb\u884c[8,9]<\/sup>\u3002\u672c\u6587\u91c7\u7528AOTF\u8fd1\u7ea2\u5916\u6280\u672f<\/a>\u5efa\u7acb\u4e86NCO\u7684\u5728\u7ebf\u68c0\u6d4b\u6a21\u578b\uff0c\u5b9e\u73b0\u4e86NCO\u542b\u91cf\u7684\u5728\u7ebf\u5feb\u901f\u68c0\u6d4b\u3002<\/p>\n 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a\u70b9\u6837\u54c1\u7f16\u53f7\uff1aa1\u3001a2\u3001a3\u3001a4\u3001a5\u00b7\u00b7\u00b7 \u00b7\u00b7\u00b7a49\u3001a50<\/p>\n b\u70b9\u6837\u54c1\u7f16\u53f7\uff1ab1\u3001b2\u3001b3\u3001b4\u3001b5\u00b7\u00b7\u00b7 \u00b7\u00b7\u00b7b49\u3001b50<\/p>\n \u2460 \u8bd5\u8f66\u5f00\u59cb\u65f6\uff0c\u6bcf5\u5206\u949f\u53d6\u4e00\u6837\u54c1\uff0c\u5171\u53d630\u4e2a\u6837\u54c1\uff1b<\/p>\n \u2461 1.5\u5c0f\u65f6\u4e4b\u540e\uff0c\u6bcf20\u5206\u949f\u53d6\u4e00\u4e2a\u6837\u54c1\uff0c\u5171\u53d66\u4e2a\u6837\u54c1\uff1b<\/p>\n \u2462 2\u5c0f\u65f6\u4e4b\u540e\uff0c\u6bcf30\u5206\u949f\u53d6\u4e00\u4e2a\u6837\u54c1\uff0c\u5171\u53d66\u4e2a\u6837\u54c1\uff1b<\/p>\n \u2463 3\u5c0f\u65f6\u4e4b\u540e\uff0c\u6bcf60\u5206\u949f\u53d6\u4e00\u4e2a\u6837\u54c1\uff0c\u5171\u53d68\u4e2a\u6837\u54c1\u3002<\/p>\n <\/p>\n \u5b9e\u9a8c\u65b9\u6cd5<\/strong><\/p>\n \u5728\u5b9e\u9a8c\u7684\u8fc7\u7a0b\u4e2d\uff0c\u7531\u4e8e\u68c0\u6d4b\u70b9\u4e0e\u53d6\u6837\u70b9\u4e4b\u95f4\u6709\u70b9\u8ddd\u79bb\uff0c\u6839\u636e\u6d41\u901f\u6211\u4eec\u8ba1\u7b97\u51fa\u5408\u9002\u7684\u53d6\u6837\u65f6\u95f4\uff0c\u68c0\u6d4b\u70b91\u5728\u626b\u63cf\u5149\u8c31\u540e2\u79d2\u949f\u53d6\u6837\uff0c\u68c0\u6d4b\u70b92\u5728\u626b\u63cf\u5149\u8c31\u540e5\u79d2\u949f\u53d6\u6837\u3002\u53d6\u6837\u65f6\uff0c\u5c06\u76f8\u5e94\u7684\u53d6\u6837\u9600\u95e8\u6253\u5f00\uff0c\u4f7f\u6db2\u4f53\u6d41\u51fa\uff0c\u7528\u5199\u597d\u5bf9\u5e94\u7f16\u53f7\u7684\u7eb8\u676f\u76db\u63a5\u3002\u53d6\u6837\u7684\u91cf\u8981\u9002\u5408\u5b9e\u9a8c\u5ba4<\/a>\u68c0\u6d4b\u7684\u9700\u8981\u5373\u53ef\uff0c\u5b9e\u9a8c\u4e2d\u53d6200ml\u5de6\u53f3\u3002\u6bcf\u53d6\u5b8c\u4e00\u4e2a\u6837\uff0c\u8981\u9a6c\u4e0a\u9001\u5f80\u5316\u9a8c\u5ba4\u68c0\u6d4b\u6570\u636e\u3002\u56e0\u77ed\u65f6\u95f4\u5185\uff0c\u6eb6\u6db2\u7684\u72b6\u6001\u4e0d\u4f1a\u53d1\u751f\u53d8\u5316\uff0c\u56e0\u6b64\u53ef\u4ee5\u8ba4\u4e3a\u626b\u63cf\u7684\u5149\u8c31\u5373\u4e3a\u6837\u54c1\u74f6\u4e2d\u7684\u6eb6\u6db2\u6837\u54c1\u7684\u5149\u8c31\u3002<\/p>\n <\/p>\n \u5728\u751f\u4ea7\u5de5\u827a\u8fbe\u5230\u6b63\u5e38\u540e\uff0c\u4e00\u822cNCO\u542b\u91cf\u5728\u9884\u805a\u5408\u53cd\u5e94\u4e2d\u6bd4\u8f83\u7a33\u5b9a\uff0c\u56e0\u6b64\u4e3a\u4e86\u53d6\u5f97\u8f83\u5927\u7684NCO\u53d8\u5316\u8303\u56f4\uff0c\u5fc5\u987b\u5728\u5f00\u59cb\u8bd5\u8f66\u65f6\u5c31\u53d6\u6837\u3002\u6db2\u4f53\u9996\u5148\u901a\u8fc7\u901a\u90531\uff0c\u6309\u7167\u53d6\u6837\u65b9\u6848\u901a\u90531\u5f00\u59cb\u626b\u63cf\u5149\u8c31\u5e76\u53d6\u6837\u3002\u5927\u7ea620min\u4e4b\u540e\uff0c\u6db2\u4f53\u5230\u8fbe\u901a\u90532\uff0c\u901a\u90532\u4e5f\u5f00\u59cb\u626b\u63cf\u5149\u8c31\u5e76\u53d6\u6837\u3002<\/p>\n \u6b64\u65f6\uff0c\u901a\u8fc7\u591a\u8def\u8f6c\u6362\u56682\u4e2a\u901a\u9053\u8f6e\u6d41\u53d6\u6837\u3002<\/p>\n <\/p>\n \u5229\u7528\u5149\u7ea4\u901a\u8fc7\u900f\u5c04\u7684\u65b9\u5f0f\u91c7\u96c6\u6837\u54c1\u7684\u5149\u8c31\u6570\u636e\u3002\u6bcf\u4e00\u5f20\u5149\u8c31\u90fd\u662f100\u6b21\u626b\u63cf\u7684\u5e73\u5747\u7ed3\u679c\u3002\u6ce2\u957f\u8303\u56f41100nm\u81f32300nm\uff0c1nm\u7684\u6ce2\u957f\u95f4\u9694\uff0c\u5149\u7a0b10mm\u3002\u5149\u8c31\u6570\u636e\u4ee5\u900f\u8fc7\u65b9\u5f0f\u91c7\u96c6\u5e76\u5904\u7406\u4e3a\u5438\u6536\u5149\u8c31\u7684\u4e00\u9636\u5fae\u5206<\/a>\u3002\u7136\u540e\u5229\u7528\u6bcf\u4e2a\u6837\u54c1NCO\u542b\u91cf\u6570\u636e\u548c\u8be5\u6837\u54c1\u7684\u5149\u8c31\u6570\u636e\u4e00\u4e00\u5bf9\u5e94\uff0c\u521b\u5efa\u6821\u6b63\u6a21\u578b\u3002<\/p>\n \u00a0<\/strong><\/p>\n \u5efa\u7acb\u6a21\u578b\u4e0e\u9884\u6d4b<\/strong><\/p>\n \u00a0<\/strong><\/p>\n \u6837\u54c1\u8fd1\u7ea2\u5916\u5149\u8c31\u7684\u91c7\u96c6<\/strong><\/p>\n \u4e3a\u83b7\u5f97\u826f\u597d\u7684\u5149\u8c31\u6570\u636e\uff0c\u5e94\u5728\u7a33\u5b9a\u4e25\u683c\u7684\u5b9e\u9a8c\u6761\u4ef6\u4e0b\u8fdb\u884c\u5149\u8c31\u626b\u63cf\uff0c\u5b9e\u9a8c\u4e2d\u626b\u63cf\u6a21\u5f0f\u8bbe\u4e3a\u201cRatio mode\u201d\uff0c\u56e0\u4e3a\u8fd9\u79cd\u65b9\u5f0f\u53ef\u4ee5\u6709\u6548\u5730\u6263\u9664\u80cc\u666f\u53d8\u5316\u5e26\u6765\u7684\u5f71\u54cd\u3002\u56fe2-\u56fe3\u5206\u522b\u662f\u901a\u90531\u548c\u901a\u90532\u6d4b\u5f97\u7684\u5178\u578bAOTF\uff0dNIR<\/a>\u539f\u59cb\u5438\u6536\u5149\u8c31\u56fe\uff08\u56fe\u4e2d\u5305\u542b50\u4e2a\u6837\u54c1\u5149\u8c31\uff09\u3002\u53ef\u4ee5\u53d1\u73b0\u56fe\u4e2d\u768450\u4e2a\u6837\u54c1\u7684\u5149\u8c31\u6392\u5217\u6bd4\u8f83\u7d27\u5bc6\uff0c\u5149\u8c31\u4e0e\u5149\u8c31\u4e4b\u95f4\u7684\u76f8\u4f3c\u6027\u8f83\u5f3a\uff0c\u91c7\u96c6\u5230\u7684\u5149\u8c31\u4fe1\u606f\u91cf\u5927\uff0c\u5149\u8c31\u6bd4\u8f83\u5177\u6709\u4ee3\u8868\u6027\u3002<\/p>\n <\/p>\n <\/p>\n \u5149\u8c31\u6570\u636e\u7684\u9884\u5904\u7406<\/strong><\/p>\n \u5728\u5efa\u7acb\u6a21\u578b\u524d\uff0c\u9996\u5148\u9700\u5bf9\u626b\u63cf\u5f97\u5230\u7684\u539f\u59cb\u5438\u6536\u5149\u8c31\u8fdb\u884c\u5149\u8c31\u9884\u5904\u7406\uff0c\u4ee5\u6d88\u9664\u566a\u97f3\u548c\u57fa\u7ebf\u7684\u5f71\u54cd\u3002\u6211\u4eec\u91c7\u7528\u7684\u9884\u5904\u7406\u65b9\u6cd5\u4e3a\u4e00\u9636\u5bfc\u65709\u70b9\u5e73\u6ed1\uff08savitzky-golay\u6cd5\uff09\u3002\u4e00\u9636\u5bfc\u6570\u5904\u7406\u53ef\u4ee5\u5f88\u597d\u7684\u6d88\u9664\u6837\u54c1\u7531\u4e8e\u989c\u8272\u5dee\u522b\u5f15\u8d77\u7684\u5149\u8c31\u57fa\u7ebf\u504f\u79fb\u548c\u6f02\u79fb\u3002\u5982\u56fe4\u3001\u56fe5\u6240\u793a\u3002<\/p>\n <\/p>\n <\/p>\n <\/p>\n \u00a0AOTF<\/strong>\uff0dNIR<\/strong>\u5b9a\u91cf\u5206\u6790\u6a21\u578b\u7684\u5efa\u7acb<\/strong><\/p>\n <\/p>\n \u5c06\u7ecf\u8fc7\u9884\u5904\u7406\u540e\u7684\u5149\u8c31\u6570\u636e\u4e0e\u6837\u54c1NCO\u5316\u9a8c\u503c\u7684\u6570\u636e\u8fdb\u884c\u5173\u8054\uff0c\u91c7\u7528\u504f\u6700\u5c0f\u4e8c\u4e58\u6cd5\uff08PLS1\uff09<\/a>\uff0c\u4ea4\u53c9\uff0d\u9a8c\u8bc1\u6cd5\uff08cross-validation\uff09\uff0c\u7528The Unscrambler\u5b9a\u91cf\u5206\u6790\u8f6f\u4ef6\u5efa\u7acb\u6a21\u578b\u3002\u5149\u8c31\u548c\u5316\u5b66\u503c\u5f02\u5e38\u503c\uff08outlier\uff09\u5206\u522b\u91c7\u7528\u5149\u8c31\u5f71\u54cd\u503cLeverage\u548c\u5316\u5b66\u503c\u8bef\u5deeResidual\u8fd9\u4e24\u4e2a\u7edf\u8ba1\u91cf\u6765\u68c0\u9a8c\u5254\u9664\u3002\u7ecf\u8fc7\u5f02\u5e38\u503c\u7684\u5254\u9664\u8fdb\u884c\u9010\u6b65\u4f18\u5316\uff0c\u6700\u540e\u5f97\u5230\u4e86\u8f83\u4e3a\u7406\u60f3\u7684\u6821\u6b63\u6a21\u578b\u3002<\/p>\n \u6240\u5f97\u7684\u901a\u90531\u548c\u901a\u90532\u7684\u8fd1\u7ea2\u5916\u9884\u6d4b\u503c\uff08Predicted\uff09\u548cNCO\u5316\u9a8c\u503c\uff08Measured\uff09\u7684\u6563\u70b9\u56fe\u5982\u56fe6-\u56fe7\u6240\u793a\u3002\u901a\u90531\u7684NCO\u6a21\u578b\u7684\u4e3b\u6210\u5206\u7ef4\u6570\u4e3a3\uff0c\u8be5\u6a21\u578b\u7684\u5185\u90e8\u4ea4\u53c9\u9a8c\u8bc1\u5747\u65b9\u5deeRMSECV=0.0047\uff0c\u76f8\u5173\u7cfb\u6570\u4e3a0.9926\uff0c\u9a8c\u8bc1\u7ed3\u679c\u5982\u56fe6\u6240\u793a\uff1b\u901a\u90532\u7684NCO\u6a21\u578b\u7684\u4e3b\u6210\u5206\u7ef4\u6570\u4e3a5\uff0c\u8be5\u6a21\u578b\u7684\u5185\u90e8\u4ea4\u53c9\u9a8c\u8bc1\u5747\u65b9\u5deeRMSECV=0.0015\uff0c\u76f8\u5173\u7cfb\u6570\u4e3a0.9996\uff0c\u9a8c\u8bc1\u7ed3\u679c\u5982\u56fe7\u6240\u793a\u3002<\/p>\n <\/p>\n <\/p>\n \u9884\u6d4b<\/strong><\/p>\n \u5229\u7528\u5efa\u7acb\u597d\u7684\u6a21\u578b\u5bf95\u4e2a\u5916\u90e8\u6837\u54c1\u8fdb\u884c\u9884\u6d4b\u3002\u9884\u6d4b\u7ed3\u679c\u89c1\u88681\u3001\u88682\u3002<\/p>\n <\/p>\n \u7ed3\u8bba<\/strong><\/p>\n <\/p>\n \u4ece\u4ee5\u4e0a\u7684\u7ed3\u679c\u53ef\u4ee5\u770b\u51fa\uff1a\u901a\u90531\u7684NCO\u6a21\u578b\u7684\u5185\u90e8\u4ea4\u53c9\u9a8c\u8bc1\u5747\u65b9\u5deeRMSECV=0.0047\uff0c\u76f8\u5173\u7cfb\u6570\u4e3a0.9926\uff0c\u5916\u90e8\u9884\u6d4b\u7684\u5e73\u5747\u7edd\u5bf9\u504f\u5dee\u4e3a0.059\uff1b\u901a\u90532\u7684NCO\u6a21\u578b\u7684\u5185\u90e8\u4ea4\u53c9\u9a8c\u8bc1\u5747\u65b9\u5deeRMSECV=0.0015\uff0c\u76f8\u5173\u7cfb\u6570\u4e3a0.9996\uff0c\u5916\u90e8\u9884\u6d4b\u7684\u5e73\u5747\u7edd\u5bf9\u504f\u5dee\u4e3a0.026\u3002\u56e0\u6b64\uff0cAOTF\u8fd1\u7ea2\u5916\u5149\u8c31\u4eea<\/a>\u5b8c\u5168\u53ef\u4ee5\u5b9e\u73b0\u5728\u7ebf\u76d1\u6d4b\u548c\u63a7\u5236\u9884\u805a\u5408\u53cd\u5e94\u8fc7\u7a0b\u4e2dNCO\u542b\u91cf\u7684\u76ee\u7684\u3002<\/p>\n \u53e6\u5916\uff0cAOTF\u8fd1\u7ea2\u5916\u5149\u8c31\u4eea\u8fd8\u53ef\u4ee5\u5728\u7ebf\u68c0\u6d4b\u6c34\u5206\u3001\u7c98\u5ea6\u7b49\u6307\u6807\u7684\u53d8\u5316\uff0c\u5982\u679c\u8fd9\u4e9b\u6307\u6807\u90fd\u5efa\u5165\u6a21\u578b\u4e2d\u53bb\uff0c\u5c31\u53ef\u4ee5\u5b9e\u73b0\u751f\u4ea7\u5728\u7ebf\u7684\u8fd1\u7ea2\u5916\u96c6\u4e2d\u63a7\u5236\u3002<\/p>\n <\/p>\n \u7ecf\u6d4e\u6548\u76ca\u5206\u6790\uff1a<\/strong><\/p>\n \u9f99\u5c71\u6c28\u7eb6\u6709\u9650\u516c\u53f8\u7684\u751f\u4ea7\u80fd\u529b\u4e3a3500\u5428\/\u5e74\uff0c\u6bcf\u5e74\u7684\u5229\u6da6\u57283000\u4e07\uff5e4000\u4e07\u4e4b\u95f4\uff0cNCO\u6307\u6807\u7684\u542b\u91cf\u662f\u8bbe\u5907\u8bd5\u8f66\u671f\u95f4\u7684\u4e3b\u8981\u68c0\u6d4b\u6307\u6807\uff0c\u867d\u7136\u91c7\u7528\u4e86\u4f4e\u8d1f\u8377\u8bd5\u8f66\u8fd0\u884c\uff0c\u4f46\u662f\u6bcf\u5e74\u7528\u4e8e\u8bd5\u8f66\u7684\u82b1\u8d39\u8fd8\u662f\u975e\u5e38\u5927\u3002\u91c7\u7528\u4e86AOTF\u5728\u7ebf\u8fd1\u7ea2\u5916<\/a>\u76d1\u63a7\u6280\u672f\u4e4b\u540e\uff0c\u5728\u5f88\u5927\u7a0b\u5ea6\u4e0a\u63d0\u9ad8\u4e86\u4e00\u6b21\u8bd5\u8f66\u7684\u6210\u529f\u7387\uff0c\u6bcf\u5e74\u53ef\u8282\u7ea6200\u4e07\u5143\u5de6\u53f3\u3002\u5b9e\u9a8c\u5ba4\u5316\u9a8cNCO\u542b\u91cf\u4f7f\u7528\u7684\u662f\u76d0\u9178\u6ef4\u5b9a\u7684\u65b9\u6cd5\uff0c\u867d\u7136\u6210\u672c\u4f4e\uff0c\u6d88\u8017\u7684\u539f\u6599\u7684\u91cf\u4e5f\u4e0d\u662f\u592a\u5927\uff0c\u4f46\u662f\u65f6\u6548\u6027\u6bd4\u8f83\u5dee\uff0c\u4e00\u822c\u5316\u9a8c\u4e00\u4e2a\u6307\u6807\u81f3\u5c11\u9700\u898140min\u3002AOTF\u5728\u7ebf\u8fd1\u7ea2\u5916\u76d1\u63a7\u4ee5\u79d2\u7ea7\u901f\u5ea6\u7ed9\u51fa\u5b9e\u65f6\u7684NCO\u542b\u91cf\u6570\u636e\uff0c\u800c\u4e14\u540c\u65f6\u8fd8\u53ef\u770b\u5230\u6bcf\u4e2a\u901a\u9053NCO\u542b\u91cf\u7684\u53d8\u5316\u8d8b\u52bf\uff0c\u65b9\u4fbf\u9ad8\u6548\u3002<\/p>\n <\/p>\n \u7f8e\u56fdBrimrose\u516c\u53f8\u7684Luminar 3060\u591a\u901a\u8defAOTF\u6280\u672f\u8fd1\u7ea2\u5916\u5149\u8c31\u4eea\u5bf9\u6c28\u7eb6\u751f\u4ea7\u9884\u805a\u5408\u8fc7\u7a0b\u4e2dNCO\u542b\u91cf\u7684\u53d8\u5316\u8fdb\u884c\u5728\u7ebf\u68c0\u6d4b\uff0c\u4ee5\u8003\u5bdf\u4eea\u5668\u5728\u7ebf\u6d4b\u8bd5\u7684\u6027\u80fd\u53ca\u6700\u7ec8\u5efa\u7acb\u8d77\u4e86\u5728\u7ebf\u68c0\u6d4b\u6a21 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