{"id":13729,"date":"2018-11-27T02:07:25","date_gmt":"2018-11-26T18:07:25","guid":{"rendered":"https:\/\/www.bihec.com\/olisclarity\/?p=13729"},"modified":"2019-05-18T00:12:44","modified_gmt":"2019-05-17T16:12:44","slug":"olis-dsm-172-cd-cpl%e7%94%a8%e4%ba%8e%e5%90%ab%e6%9c%89%e6%89%8b%e6%80%a7%e7%a1%bc%e4%bd%9c%e4%b8%ba%e7%ab%8b%e4%bd%93%e5%8d%95%e5%85%83%e7%9a%84%e7%a1%bc%e9%85%b8%e8%a1%8d%e7%94%9f","status":"publish","type":"post","link":"https:\/\/www.bihec.com\/olisclarity\/olis-dsm-172-cd-cpl%e7%94%a8%e4%ba%8e%e5%90%ab%e6%9c%89%e6%89%8b%e6%80%a7%e7%a1%bc%e4%bd%9c%e4%b8%ba%e7%ab%8b%e4%bd%93%e5%8d%95%e5%85%83%e7%9a%84%e7%a1%bc%e9%85%b8%e8%a1%8d%e7%94%9f\/","title":{"rendered":"OLIS DSM 172 CD & CPL\u7528\u4e8e\u201c\u542b\u6709\u624b\u6027\u787c\u4f5c\u4e3a\u7acb\u4f53\u5355\u5143\u7684\u787c\u9178\u884d\u751f\u7684\u4e9a\u6c34\u6768\u57fa\u8159\u914d\u5408\u7269\u7684\u5706\u504f\u632f\u53d1\u5149\u201d"},"content":{"rendered":"

OLIS DSM 172<\/a> CD<\/a> & CPL<\/a>\u7528\u4e8e\u201c\u542b\u6709\u624b\u6027\u787c\u4f5c\u4e3a\u7acb\u4f53\u5355\u5143\u7684\u787c\u9178\u884d\u751f\u7684\u4e9a\u6c34\u6768\u57fa\u8159\u914d\u5408\u7269\u7684\u5706\u504f\u632f\u53d1\u5149<\/a>\u201d<\/p>\n

Circularly Polarized Luminescence of Boronic Acid-Derived Salicylidenehydrazone Complexes Containing Chiral Boron as Stereogenic Unit<\/a><\/p>\n

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Racemic mixtures of boronic acid-derived salicylidenehydrazone (BASHY) complexes were enantiomerically resolved. The chiroptical properties of the stereoisomers, containing an asymmetric boron as the only stereogenic unit, are translated into mirror-imaged electronic circular dichroism spectra and circularly polarized luminescence (CPL, dissymmetry factors of 3\u20135 \u00d7 10\u20134<\/sup>) is observed. The spectral position of the CPL emission is determined by the push\u2013pull character of the dye. These features expand the functional scope of the brightly emitting BASHY dye platform.<\/p>\n<\/div>\n<\/div>\n

\u5c06\u787c\u9178\u884d\u751f\u7684\u4e9a\u6c34\u6768\u57fa\u8159\uff08BASHY\uff09\u7edc\u5408\u7269\u7684\u5916\u6d88\u65cb\u6df7\u5408\u7269\u8fdb\u884c\u5bf9\u6620\u4f53\u62c6\u5206\u3002 \u542b\u6709\u4e0d\u5bf9\u79f0\u787c\u4f5c\u4e3a\u552f\u4e00\u7acb\u4f53\u5f02\u6784\u5355\u5143\u7684\u7acb\u4f53\u5f02\u6784\u4f53\u7684\u624b\u6027\u7279\u6027\u88ab\u8f6c\u5316\u4e3a\u955c\u50cf\u7535\u5b50\u5706\u4e8c\u8272\u5149\u8c31<\/a>\uff0c\u5e76\u89c2\u5bdf\u5230\u5706\u504f\u632f\u53d1\u5149\uff08CPL\uff0c3-5\u00d710-4\u7684\u4e0d\u5bf9\u79f0\u56e0\u5b50\uff09\u3002 CPL\u53d1\u5c04\u7684\u5149\u8c31\u4f4d\u7f6e\u7531\u67d3\u6599\u7684\u63a8\u633d\u7279\u6027\u51b3\u5b9a\u3002 \u8fd9\u4e9b\u529f\u80fd\u6269\u5c55\u4e86\u660e\u4eae\u53d1\u5149\u7684BASHY\u67d3\u6599\u5e73\u53f0\u7684\u529f\u80fd\u8303\u56f4\u3002<\/div>\n
<\/div>\n
https:\/\/pubs.acs.org\/doi\/abs\/10.1021\/acs.joc.8b01844<\/a><\/div>\n

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CD\u5149\u8c31\u4eea<\/a>\n\u5706\u4e8c\u8272<\/a>\n\u5706\u4e8c\u8272CD<\/a>\n\u5706\u4e8c\u8272\u5149\u8c31\u4eea<\/a>\n\u5706\u4e8c\u8272\u8c31<\/a><\/div>","protected":false},"excerpt":{"rendered":"

OLIS DSM 172 CD & CPL\u7528\u4e8e\u201c\u542b\u6709\u624b\u6027\u787c\u4f5c\u4e3a\u7acb\u4f53\u5355\u5143\u7684\u787c\u9178\u884d\u751f\u7684\u4e9a\u6c34\u6768\u57fa\u8159\u914d\u5408\u7269\u7684\u5706\u504f\u632f\u53d1\u5149\u201d Circularly Polarized Luminesc <\/p>\n","protected":false},"author":1,"featured_media":13730,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":[],"categories":[1],"tags":[15,11,18,4,12],"_links":{"self":[{"href":"https:\/\/www.bihec.com\/olisclarity\/wp-json\/wp\/v2\/posts\/13729"}],"collection":[{"href":"https:\/\/www.bihec.com\/olisclarity\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.bihec.com\/olisclarity\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.bihec.com\/olisclarity\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.bihec.com\/olisclarity\/wp-json\/wp\/v2\/comments?post=13729"}],"version-history":[{"count":0,"href":"https:\/\/www.bihec.com\/olisclarity\/wp-json\/wp\/v2\/posts\/13729\/revisions"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/www.bihec.com\/olisclarity\/wp-json\/wp\/v2\/media\/13730"}],"wp:attachment":[{"href":"https:\/\/www.bihec.com\/olisclarity\/wp-json\/wp\/v2\/media?parent=13729"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.bihec.com\/olisclarity\/wp-json\/wp\/v2\/categories?post=13729"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.bihec.com\/olisclarity\/wp-json\/wp\/v2\/tags?post=13729"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}