{"id":13776,"date":"2019-02-18T23:34:59","date_gmt":"2019-02-18T15:34:59","guid":{"rendered":"https:\/\/www.bihec.com\/olisclarity\/?p=13776"},"modified":"2019-04-12T09:46:38","modified_gmt":"2019-04-12T01:46:38","slug":"%e5%90%ab%e6%9c%89%e6%89%8b%e6%80%a7%e4%ba%9a%e7%a0%9c%e7%9a%84o-ope%e4%b8%8e%e9%87%91%e5%b1%9e%e9%98%b3%e7%a6%bb%e5%ad%90%e7%9a%84%e4%ba%b2%e6%b0%a7%e4%bd%9c%e7%94%a8%e8%b0%83%e6%8e%a7cpl%e5%9c%86","status":"publish","type":"post","link":"https:\/\/www.bihec.com\/olisclarity\/%e5%90%ab%e6%9c%89%e6%89%8b%e6%80%a7%e4%ba%9a%e7%a0%9c%e7%9a%84o-ope%e4%b8%8e%e9%87%91%e5%b1%9e%e9%98%b3%e7%a6%bb%e5%ad%90%e7%9a%84%e4%ba%b2%e6%b0%a7%e4%bd%9c%e7%94%a8%e8%b0%83%e6%8e%a7cpl%e5%9c%86\/","title":{"rendered":"\u542b\u6709\u624b\u6027\u4e9a\u781c\u7684o-OPE\u4e0e\u91d1\u5c5e\u9633\u79bb\u5b50\u7684\u4eb2\u6c27\u4f5c\u7528\u8c03\u63a7CPL\u5706\u504f\u632f\u53d1\u5149"},"content":{"rendered":"

OFF\/ON switching of circularly polarized luminescence by oxophilic interaction of homochiral sulfoxide-containing o-OPEs with metal cations<\/p>\n

\"\"<\/p>\n

\n

Here we describe a new class of CPL<\/a> switches based on oxophilic interactions between chiral sulfoxide-containing\u00a0ortho<\/em>-phenylene ethynylene (o<\/em>-OPE) foldamers and cationic metals. These systems represent a unique case combining high\u00a0g<\/em>lum<\/sub><\/small>\u00a0values (up to 0.7 \u00d7 10\u22122<\/sup><\/small>) and high quantum yields in both folded ON and unfolded OFF CPL states.<\/p>\n

\"\"<\/a><\/p>\n<\/div>\n

CD\u5149\u8c31\u4eea<\/a>\n\u5438\u6536\u5149\u8c31\u4eea<\/a>\n\u5706\u4e8c\u8272\u5149\u8c31\u4eea<\/a>\n\u5706\u504f\u632f\u5149\u8c31\u4eea<\/a>\n\u8367\u5149\u5149\u8c31\u4eea<\/a><\/div>","protected":false},"excerpt":{"rendered":"

OFF\/ON switching of circularly polarized luminescence by oxophilic interaction of homochir <\/p>\n","protected":false},"author":1,"featured_media":13777,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"_vp_format_video_url":"","_vp_image_focal_point":[]},"categories":[1],"tags":[15,16,4,14,17],"yoast_head":"\n\u542b\u6709\u624b\u6027\u4e9a\u781c\u7684o-OPE\u4e0e\u91d1\u5c5e\u9633\u79bb\u5b50\u7684\u4eb2\u6c27\u4f5c\u7528\u8c03\u63a7CPL\u5706\u504f\u632f\u53d1\u5149 - CPL\u5706\u504f\u632f\u8367\u5149\u5149\u8c31\u4eea CD\u5706\u4e8c\u8272\u5149\u8c31\u4eea Olis<\/title>\n<meta name=\"robots\" content=\"index, follow, max-snippet:-1, max-image-preview:large, max-video-preview:-1\" \/>\n<link rel=\"canonical\" href=\"https:\/\/www.bihec.com\/olisclarity\/\u542b\u6709\u624b\u6027\u4e9a\u781c\u7684o-ope\u4e0e\u91d1\u5c5e\u9633\u79bb\u5b50\u7684\u4eb2\u6c27\u4f5c\u7528\u8c03\u63a7cpl\u5706\/\" \/>\n<meta property=\"og:locale\" content=\"zh_CN\" \/>\n<meta property=\"og:type\" content=\"article\" \/>\n<meta property=\"og:title\" content=\"\u542b\u6709\u624b\u6027\u4e9a\u781c\u7684o-OPE\u4e0e\u91d1\u5c5e\u9633\u79bb\u5b50\u7684\u4eb2\u6c27\u4f5c\u7528\u8c03\u63a7CPL\u5706\u504f\u632f\u53d1\u5149 - 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