{"id":13891,"date":"2020-03-27T12:49:03","date_gmt":"2020-03-27T04:49:03","guid":{"rendered":"https:\/\/www.bihec.com\/olisclarity\/?p=13891"},"modified":"2020-03-27T12:49:03","modified_gmt":"2020-03-27T04:49:03","slug":"%e9%bb%91%e9%be%99%e6%b1%9f%e5%a4%a7%e5%ad%a6jacs%ef%bc%9a%e9%ab%98%e5%8f%91%e5%85%89%e6%80%a7%e8%83%bd%e7%9a%84%e6%89%8b%e6%80%a7%e5%9b%9b%e9%9d%a2%e4%bd%93eu4l4l14%e7%ac%bc%ef%bc%9a%e6%89%8b","status":"publish","type":"post","link":"https:\/\/www.bihec.com\/olisclarity\/%e9%bb%91%e9%be%99%e6%b1%9f%e5%a4%a7%e5%ad%a6jacs%ef%bc%9a%e9%ab%98%e5%8f%91%e5%85%89%e6%80%a7%e8%83%bd%e7%9a%84%e6%89%8b%e6%80%a7%e5%9b%9b%e9%9d%a2%e4%bd%93eu4l4l14%e7%ac%bc%ef%bc%9a%e6%89%8b\/","title":{"rendered":"\u9ed1\u9f99\u6c5f\u5927\u5b66JACS\uff1a\u9ad8\u53d1\u5149\u6027\u80fd\u7684\u624b\u6027\u56db\u9762\u4f53Eu4L4(L1)4\u7b3c\uff1a\u624b\u6027\u8bf1\u5bfc\uff0c\u624b\u6027\u8bb0\u5fc6\u548c\u5706\u504f\u632f\u53d1\u5149"},"content":{"rendered":"<p>\u5177\u6709<a href=\"https:\/\/www.bihec.com\/olisclarity\/tag\/%e5%9c%86%e5%81%8f%e6%8c%af%e5%8f%91%e5%85%89\/\" title=\"View all posts in \u5706\u504f\u632f\u53d1\u5149\" target=\"_blank\">\u5706\u504f\u632f\u53d1\u5149<\/a>\uff08<a href=\"https:\/\/www.bihec.com\/olisclarity\/tag\/cpl\/\" title=\"View all posts in CPL\" target=\"_blank\">CPL<\/a>\uff09\u6027\u8d28\u7684\u624b\u6027\u9567\u7cfb\u5143\u7d20\u7b3c\u5728\u5bf9\u6620\u4f53\u9009\u62e9\u6027\u5ba2\u4f53\u8bc6\u522b\u548c\u4f20\u611f\u4e2d\u5177\u6709\u6f5c\u5728\u7684\u5e94\u7528\u3002\u7136\u800c\uff0c\u9274\u4e8eLn(III)\u79bb\u5b50\u7684\u4e0d\u7a33\u5b9a\u6027\uff0c\u5f00\u53d1\u4e00\u79cd\u7b80\u5355\u800c\u53ef\u9760\u7684\u65b9\u6cd5\u7528\u4e8e\u540c\u578b\u624b\u6027\u9567\u7cfb\u5143\u7d20\u7b3c\u7684\u975e\u5bf9\u6620\u9009\u62e9\u6027\u7ec4\u88c5\u4ecd\u7136\u662f\u4e00\u4e2a\u5de8\u5927\u7684\u6311\u6218\u3002\u8fd1\u65e5\uff0c\u9ed1\u9f99\u6c5fPengfei Yan\uff0cHongfeng Li\u7b49\u62a5\u9053\u4e86\u901a\u8fc7\u624b\u6027\u8f85\u52a9\u914d\u4f53\u8bf1\u5bfc\u7b56\u7565\u5f62\u6210\u5bf9\u6620\u7eaf\u9567\u7cfb\u56db\u9762\u4f53\u7b3c\u7684\u7b2c\u4e00\u4e2a\u4f8b\u5b50\u3002\u5408\u6210\u7684[(Eu<sub>4<\/sub>L<sub>4<\/sub>)(R\/S-BINAPO)<sub>4<\/sub>]\u7b3c\u662f\u7531\u56db\u4e2a\u975e\u624b\u6027C<sub>3<\/sub>\u5bf9\u79f0\u7684[4,4&#8242;,4&#8221;-tri(4,4,4-trifluoro-1,3-dioxobutyl)triphenylamine, L)]\u4e3a\u9762\uff0c\u56db\u4e2aEu(III)\u79bb\u5b50\u4e3a\u9876\u70b9\uff0c\u548c\u56db\u4e2a\u624b\u6027R\/S-bis(diphenylphosphoryl)-1,1\u2032-binaphthyl (R\/S-BINAPO)\u4f5c\u4e3a\u8f85\u52a9\u914d\u4f53\u7ec4\u6210\u3002\u4f5c\u8005\u901a\u8fc7X\u5c04\u7ebf\u6676\u4f53\u5b66\uff0cNMR\u548c<a href=\"https:\/\/www.bihec.com\/olisclarity\/tag\/cd\/\" title=\"View all posts in CD\" target=\"_blank\">CD<\/a>\u5149\u8c31\u5bf9\u5bf9\u6620\u7eaf\u7684\u624b\u6027\u62d3\u6251\u56db\u9762\u4f53\u7b3c(Eu<sub>4<\/sub>L<sub>4<\/sub>)(R-BINAPO)<sub>4<\/sub>\u7684(Eu<sub>4<\/sub>L<sub>4<\/sub>)(S-BINAPO)<sub>4<\/sub>\u00a0(\u0394\u0394\u0394\u0394-1\u548c\u039b\u039b\u039b\u039b-1)\u8fdb\u884c\u4e86\u8868\u5f81\u3002\u5b9e\u9a8c\u53d1\u73b0\uff0c\u8be5\u56db\u9762\u4f53\u7b3c\u5177\u6709\u5f3a\u7684CPL\uff0c|glum|\u9ad8\u8fbe0.20\uff0c\u4e14\u91cf\u5b50\u4ea7\u7387\uff08QYs\uff09\u9ad8\u8fbe81\uff05\uff0c\u8fd9\u662f\u624b\u6027Ln(III)\u914d\u5408\u7269\u4e2d\u62a5\u9053\u7684\u6700\u9ad8\u503c\u3002\u6b64\u5916\uff0c\u4f5c\u8005\u8fd8\u9996\u6b21\u89c2\u5bdf\u5230\u57fa\u4e8e\u9567\u7cfb\u5143\u7d20\u7684\u7ec4\u88c5\u7684\u624b\u6027\u8bb0\u5fc6\u6548\u5e94\u3002\u5f53R\/S-BINAPO\u88ab\u975e\u624b\u6027bis[2-(diphenylphosphino)phenyl]\uff08DPEPO\uff09\u53d6\u4ee3\u540e\uff0c\u8be5\u7b3c\u7684\u624b\u6027\u53ef\u4ee5\u4fdd\u7559\uff0c\u5f97\u5230\u4e86\u53e6\u4e00\u5bf9\u5bf9\u6620\u7eafEu(III)\u56db\u9762\u4f53\u7b3c\u578b\u0394\u0394\u0394\u0394-\u548c\u039b\u039b\u039b\u039b-[(Eu<sub>4<\/sub>L<sub>4<\/sub>)(DPEPO)<sub>4<\/sub>] (\u0394\u0394\u0394\u0394-2\u548c\u039b\u039b\u039b\u039b-2)\u3002\u4ee4\u4eba\u610f\u5916\u7684\u662f\uff0c\u0394\u0394\u0394\u0394-2\u548c\u039b\u039b\u039b\u039b-2\u5177\u6709\u9ad8\u7684\u53d1\u5149\u91cf\u5b50\u4ea7\u7387\uff08QYs = 68\uff05\uff09\u548c\u5f3a\u7684CPL\uff08|glum| = 0.10\uff09\u3002\u8be5\u5de5\u4f5c\u4e3a\u5236\u5907\u5177\u6709CPL\u6027\u8d28\u7684\u9567\u7cfb\u5143\u7d20\u7b3c\u63d0\u4f9b\u4e86\u4e00\u79cd\u7b80\u5355\u4e14\u4f4e\u6210\u672c\u7684\u5408\u6210\u7b56\u7565\u3002<\/p>\n<p><img loading=\"lazy\" class=\"alignnone wp-image-13892 size-full\" src=\"https:\/\/www.bihec.com\/olisclarity\/wp-content\/uploads\/sites\/7\/2020\/03\/1574398257160952.png\" alt=\"\" width=\"378\" height=\"191\" srcset=\"https:\/\/www.bihec.com\/olisclarity\/wp-content\/uploads\/sites\/7\/2020\/03\/1574398257160952.png?v=1585284409 378w, https:\/\/www.bihec.com\/olisclarity\/wp-content\/uploads\/sites\/7\/2020\/03\/1574398257160952-300x152.png?v=1585284409 300w\" sizes=\"(max-width: 378px) 100vw, 378px\" \/><\/p>\n<p><a>Yanyan Zhou, Hongfeng Li,* Pengfei Yan*, et al.\u00a0<\/a>A Highly Luminescent Chiral Tetrahedral Eu<sub>4<\/sub>L<sub>4<\/sub>(L&#8217;)<sub>4<\/sub>\u00a0Cage: Chirality Induction, Chirality memory and Circularly Polarized Luminescence. J. Am. Chem. Soc., 2019<\/p>\n<p>DOI:\u00a010.1021\/jacs.9b07178<\/p>\n<p><a href=\"https:\/\/pubs.acs.org\/doi\/10.1021\/jacs.9b07178\">https:\/\/pubs.acs.org\/doi\/10.1021\/jacs.9b07178<\/a><\/p>\n<br><div class=\"tagcloud\"><a href=\"https:\/\/www.bihec.com\/olisclarity\/tag\/cpl\/\" class=\"tag-cloud-link tag-link-0 tag-link-position-1\" style=\"font-size: 22pt;\" aria-label=\"CPL (2\u4e2a\u9879\u76ee)\">CPL<\/a>\n<a href=\"https:\/\/www.bihec.com\/olisclarity\/tag\/%e5%9c%86%e5%81%8f%e6%8c%af%e5%8f%91%e5%85%89%e5%85%89%e8%b0%b1%e4%bb%aa\/\" class=\"tag-cloud-link tag-link-1 tag-link-position-2\" style=\"font-size: 8pt;\" aria-label=\"\u5706\u504f\u632f\u53d1\u5149\u5149\u8c31\u4eea (1\u4e2a\u9879\u76ee)\">\u5706\u504f\u632f\u53d1\u5149\u5149\u8c31\u4eea<\/a>\n<a href=\"https:\/\/www.bihec.com\/olisclarity\/tag\/%e6%89%8b%e6%80%a7%e8%ae%b0%e5%bf%86%e5%92%8c%e5%9c%86%e5%81%8f%e6%8c%af%e5%8f%91%e5%85%89\/\" class=\"tag-cloud-link tag-link-2 tag-link-position-3\" style=\"font-size: 8pt;\" aria-label=\"\u624b\u6027\u8bb0\u5fc6\u548c\u5706\u504f\u632f\u53d1\u5149 (1\u4e2a\u9879\u76ee)\">\u624b\u6027\u8bb0\u5fc6\u548c\u5706\u504f\u632f\u53d1\u5149<\/a>\n<a href=\"https:\/\/www.bihec.com\/olisclarity\/tag\/%e6%89%8b%e6%80%a7%e8%af%b1%e5%af%bc\/\" class=\"tag-cloud-link tag-link-3 tag-link-position-4\" style=\"font-size: 8pt;\" aria-label=\"\u624b\u6027\u8bf1\u5bfc (1\u4e2a\u9879\u76ee)\">\u624b\u6027\u8bf1\u5bfc<\/a>\n<a href=\"https:\/\/www.bihec.com\/olisclarity\/tag\/%e9%ab%98%e5%8f%91%e5%85%89%e6%80%a7%e8%83%bd%e7%9a%84%e6%89%8b%e6%80%a7%e5%9b%9b%e9%9d%a2%e4%bd%93eu4l4l14%e7%ac%bc\/\" class=\"tag-cloud-link tag-link-4 tag-link-position-5\" style=\"font-size: 8pt;\" aria-label=\"\u9ad8\u53d1\u5149\u6027\u80fd\u7684\u624b\u6027\u56db\u9762\u4f53Eu4L4(L1)4\u7b3c (1\u4e2a\u9879\u76ee)\">\u9ad8\u53d1\u5149\u6027\u80fd\u7684\u624b\u6027\u56db\u9762\u4f53Eu4L4(L1)4\u7b3c<\/a>\n<a href=\"https:\/\/www.bihec.com\/olisclarity\/tag\/%e9%bb%91%e9%be%99%e6%b1%9f%e5%a4%a7%e5%ad%a6jacs\/\" class=\"tag-cloud-link tag-link-5 tag-link-position-6\" style=\"font-size: 8pt;\" aria-label=\"\u9ed1\u9f99\u6c5f\u5927\u5b66JACS (1\u4e2a\u9879\u76ee)\">\u9ed1\u9f99\u6c5f\u5927\u5b66JACS<\/a><\/div>","protected":false},"excerpt":{"rendered":"<p>\u5177\u6709\u5706\u504f\u632f\u53d1\u5149\uff08CPL\uff09\u6027\u8d28\u7684\u624b\u6027\u9567\u7cfb\u5143\u7d20\u7b3c\u5728\u5bf9\u6620\u4f53\u9009\u62e9\u6027\u5ba2\u4f53\u8bc6\u522b\u548c\u4f20\u611f\u4e2d\u5177\u6709\u6f5c\u5728\u7684\u5e94\u7528\u3002\u7136\u800c\uff0c\u9274\u4e8eLn(III)\u79bb\u5b50\u7684\u4e0d\u7a33\u5b9a\u6027\uff0c\u5f00\u53d1\u4e00\u79cd\u7b80\u5355\u800c\u53ef\u9760\u7684\u65b9\u6cd5\u7528\u4e8e\u540c\u578b\u624b\u6027\u9567\u7cfb\u5143\u7d20\u7b3c\u7684\u975e <\/p>\n","protected":false},"author":7,"featured_media":13892,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":[],"categories":[1],"tags":[116,117,115,114,113,112],"_links":{"self":[{"href":"https:\/\/www.bihec.com\/olisclarity\/wp-json\/wp\/v2\/posts\/13891"}],"collection":[{"href":"https:\/\/www.bihec.com\/olisclarity\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.bihec.com\/olisclarity\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.bihec.com\/olisclarity\/wp-json\/wp\/v2\/users\/7"}],"replies":[{"embeddable":true,"href":"https:\/\/www.bihec.com\/olisclarity\/wp-json\/wp\/v2\/comments?post=13891"}],"version-history":[{"count":1,"href":"https:\/\/www.bihec.com\/olisclarity\/wp-json\/wp\/v2\/posts\/13891\/revisions"}],"predecessor-version":[{"id":13893,"href":"https:\/\/www.bihec.com\/olisclarity\/wp-json\/wp\/v2\/posts\/13891\/revisions\/13893"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/www.bihec.com\/olisclarity\/wp-json\/wp\/v2\/media\/13892"}],"wp:attachment":[{"href":"https:\/\/www.bihec.com\/olisclarity\/wp-json\/wp\/v2\/media?parent=13891"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.bihec.com\/olisclarity\/wp-json\/wp\/v2\/categories?post=13891"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.bihec.com\/olisclarity\/wp-json\/wp\/v2\/tags?post=13891"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}