{"id":14074,"date":"2020-07-15T09:21:59","date_gmt":"2020-07-15T01:21:59","guid":{"rendered":"https:\/\/www.bihec.com\/olisclarity\/?p=14074"},"modified":"2020-07-15T09:40:28","modified_gmt":"2020-07-15T01:40:28","slug":"synthesis-of-enantiopure-lanthanide-complexes-supported","status":"publish","type":"post","link":"https:\/\/www.bihec.com\/olisclarity\/synthesis-of-enantiopure-lanthanide-complexes-supported\/","title":{"rendered":"Ung\u5b9e\u9a8c\u5ba4\u4f7f\u7528CPL SOLO\u5706\u504f\u632f\u8367\u5149\u5149\u8c31\u4eea\u53d1\u8868\u7b2c\u4e8c\u7bc7InorgChem\u8bba\u6587\uff1aSynthesis of Enantiopure Lanthanide Complexes Supported by Hexadentate N,N\u2032-Bis(methylbipyridyl)bipyrrolidine and Their Circularly Polarized Luminescence"},"content":{"rendered":"<p>David Schnable, Kelila Freedman, Kaitlynn M. Ayers, Nathan D. Schley, Moshe Kol, and Ga\u00ebl Ung*<\/p>\n<h2>Abstract<\/h2>\n<p>We report the synthesis of lanthanide complexes supported by enantiopure N,N\u2032-bis(methylbipyridyl)bipyrrolidine and subsequent characterization through luminescence studies. Complexes of this ligand with the visibly emissive lanthanides Sm, Eu, Tb, and Dy are luminescent (\u03d5f of \u22640.32) and demonstrate strong preferential emission of circularly polarized light in all four cases (|glum| of \u22640.26). Notably, all four possess at least one transition with a |glum| of &gt;0.2, and the strongest preferential emission is measured from the complexes of Sm and Dy.<\/p>\n<p>[pdfjs-viewer url=&#8221;https%3A%2F%2Fwww.bihec.com%2Folisclarity%2Fwp-content%2Fuploads%2Fsites%2F7%2F2020%2F07%2Fic0c00946_si_001.pdf&#8221; viewer_width=100% viewer_height=1360px fullscreen=true download=true print=true]<\/p>\n<br><div class=\"tagcloud\"><a href=\"https:\/\/www.bihec.com\/olisclarity\/tag\/cpl-solo\/\" class=\"tag-cloud-link tag-link-0 tag-link-position-1\" style=\"font-size: 12.590163934426pt;\" aria-label=\"CPL Solo (4\u4e2a\u9879\u76ee)\">CPL Solo<\/a>\n<a href=\"https:\/\/www.bihec.com\/olisclarity\/tag\/inorgchem\/\" class=\"tag-cloud-link tag-link-1 tag-link-position-2\" style=\"font-size: 8pt;\" aria-label=\"InorgChem (1\u4e2a\u9879\u76ee)\">InorgChem<\/a>\n<a href=\"https:\/\/www.bihec.com\/olisclarity\/tag\/ung%e5%ae%9e%e9%aa%8c%e5%ae%a4\/\" class=\"tag-cloud-link tag-link-2 tag-link-position-3\" style=\"font-size: 8pt;\" aria-label=\"Ung\u5b9e\u9a8c\u5ba4 (1\u4e2a\u9879\u76ee)\">Ung\u5b9e\u9a8c\u5ba4<\/a>\n<a href=\"https:\/\/www.bihec.com\/olisclarity\/tag\/%e5%9c%86%e5%81%8f%e6%8c%af%e8%8d%a7%e5%85%89%e5%85%89%e8%b0%b1%e4%bb%aa\/\" class=\"tag-cloud-link tag-link-3 tag-link-position-4\" style=\"font-size: 22pt;\" aria-label=\"\u5706\u504f\u632f\u8367\u5149\u5149\u8c31\u4eea (32\u4e2a\u9879\u76ee)\">\u5706\u504f\u632f\u8367\u5149\u5149\u8c31\u4eea<\/a><\/div>","protected":false},"excerpt":{"rendered":"<p>David Schnable, Kelila Freedman, Kaitlynn M. Ayers, Nathan D. Schley, Moshe Kol, and Ga\u00ebl  <\/p>\n","protected":false},"author":7,"featured_media":14075,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":[],"categories":[1],"tags":[19,162,161,7],"_links":{"self":[{"href":"https:\/\/www.bihec.com\/olisclarity\/wp-json\/wp\/v2\/posts\/14074"}],"collection":[{"href":"https:\/\/www.bihec.com\/olisclarity\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.bihec.com\/olisclarity\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.bihec.com\/olisclarity\/wp-json\/wp\/v2\/users\/7"}],"replies":[{"embeddable":true,"href":"https:\/\/www.bihec.com\/olisclarity\/wp-json\/wp\/v2\/comments?post=14074"}],"version-history":[{"count":2,"href":"https:\/\/www.bihec.com\/olisclarity\/wp-json\/wp\/v2\/posts\/14074\/revisions"}],"predecessor-version":[{"id":14080,"href":"https:\/\/www.bihec.com\/olisclarity\/wp-json\/wp\/v2\/posts\/14074\/revisions\/14080"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/www.bihec.com\/olisclarity\/wp-json\/wp\/v2\/media\/14075"}],"wp:attachment":[{"href":"https:\/\/www.bihec.com\/olisclarity\/wp-json\/wp\/v2\/media?parent=14074"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.bihec.com\/olisclarity\/wp-json\/wp\/v2\/categories?post=14074"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.bihec.com\/olisclarity\/wp-json\/wp\/v2\/tags?post=14074"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}