{"id":1511870,"date":"2019-12-26T17:39:50","date_gmt":"2019-12-26T09:39:50","guid":{"rendered":"https:\/\/www.bihec.com\/omnical\/?p=1511870"},"modified":"2019-12-26T17:39:50","modified_gmt":"2019-12-26T09:39:50","slug":"%e9%87%8f%e7%83%ad%e4%bb%aa-%e5%be%ae%e9%87%8f%e7%83%ad-%e7%bb%9d%e7%83%ad%e5%8a%a0%e9%80%9f%e9%87%8f%e7%83%ad%e4%bb%aa-%e7%b2%be%e7%bb%86%e5%8c%96%e5%b7%a5%e5%8f%8d%e5%ba%94%e5%ae%89%e5%85%a8","status":"publish","type":"post","link":"https:\/\/www.bihec.com\/omnical\/%e9%87%8f%e7%83%ad%e4%bb%aa-%e5%be%ae%e9%87%8f%e7%83%ad-%e7%bb%9d%e7%83%ad%e5%8a%a0%e9%80%9f%e9%87%8f%e7%83%ad%e4%bb%aa-%e7%b2%be%e7%bb%86%e5%8c%96%e5%b7%a5%e5%8f%8d%e5%ba%94%e5%ae%89%e5%85%a8\/","title":{"rendered":"\u91cf\u70ed\u4eea\/\u5fae\u91cf\u70ed\/\u7edd\u70ed\u52a0\u901f\u91cf\u70ed\u4eea\/\u7cbe\u7ec6\u5316\u5de5\u53cd\u5e94\u5b89\u5168\u91cf\u70ed"},"content":{"rendered":"

DARC<\/a> \u662f\u5168\u7403\u6700\u5148\u8fdb\u7684100%\u7edd\u70ed\u52a0\u901f \u91cf\u70ed\u4eea<\/a>\u3002\u8be5\u7cfb\u7edf\u80fd\u591f\u5b9e\u6d4b\u5230\u7406\u8bba\u6e29\u5347\u548c\u771f\u5b9e \u7684\u6700\u5927\u53cd\u5e94\u901f\u7387<\/a>\u65f6\u95f4\uff0c\u800c\u52ff\u9700\u8fdb\u884c\u5bb9\u5668\u70ed\u5bb9 \u6821\u6b63\u3002<\/p>\n

\u25ce 100\uff05\u7edd\u70ed \u0394T\uff0c\u0394P\uff0cdT\/dt\uff0cdP\/dt\uff0cTonset<\/a>\uff0cTmax\uff0cTMR<\/a> \u4e00\u7ecf\u6d4b\u91cf\uff0c\u65e0\u9700\u8fdb\u884c\u4efb\u4f55phi\u6821\u6b63 TM<\/p>\n

\u25ce \u9ad8\u5ea6 \u81ea\u52a8\u5316\uff0cDARC \u5141\u8bb8\u65e0\u4eba\u503c\u5b88\u64cd\u4f5c<\/p>\n

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\u25ce \u66f4\u9ad8\u7684\u6700\u7ec8\u7edd\u70ed\u6e29\u5347<\/a>\uff08Tmax<\/p>\n

 <\/p>\n

DARC phi=1\u66f2\u7ebf\u4e0e\u5931\u771f\u7684ARC\u66f2\u7ebf\u6bd4\u8f83<\/strong><\/p>\n

\u5728\u4f20\u7edf\u7684ARC\u5b9e\u9a8c\u4e2d\uff0c\u6837\u54c1\u5bb9\u5668\u7684\u5438\u70ed\u6548\u5e94\u6216 phi\u56e0\u5b50\u6548\u5e94\u662f\u4e00\u4e2a\u4e3b\u8981\u7684\u963b\u788d\u53c2\u6570\uff0c\u5b83\u4f1a\u964d\u4f4e ARC\u7684\u6574\u4f53\u70ed\u5316\u5b66\u6d4b\u91cf\u7075\u654f\u5ea6\u5e76\u5ef6\u957fARC\u6d4b\u8bd5\u6301 \u7eed\u65f6\u95f4\u3002
\n\u5728\u5de6\u56fe\u4e2d\uff0c\u5177\u6709\u5927\u7684phi\u56e0\u5b50\u7684\u5e38\u89c4ARC\u51e0\u4e4e\u4e0d\u80fd \u68c0\u6d4b\u5230\u524d\u9762\u7684\u53cd\u5e94\u3002
\n\u76f8\u6bd4\u4e4b\u4e0b\uff0c\u7531\u4e8e100\uff05\u6d88\u9664\u4e86\u6837\u54c1\u5bb9\u5668\u7684\u5438\u70ed\u6548 TM\u679c\uff0c\u201c\u96f6 \u70ed\u5bb9\u5bb9\u5668\u201dDARC \u53ef\u4ee5\u66f4\u65e9\u5730\u6d4b\u91cf\u8d77\u59cb \u6e29\u5ea6\u3002\u6700\u7ec8\u6e29\u5347\u8d8a\u9ad8\uff0cTMR\u503c\u8d8a\u5c0f\u8d8a\u771f\u5b9e\u3002 \u6b64 \u5916\uff0c\u7531\u4e8e\u6d88\u9664\u4e86\u5bb9\u5668\u5438\u70ed\u6548\u5e94\uff0c\u53ef\u4ee5\u5728\u8be5\u5dee\u5206\u7edd\u70ed \u8865\u507f\u91cf\u70ed\u8ba1\u4e0a\u6d4b\u8bd5\u6d53\u5ea6\u66f4\u4f4e\u7684\u6837\u54c1\u548c\u5177\u6709\u4f4e\u653e\u70ed\u6d3b \u6027\u7684\u6837\u54c1\u3002<\/p>\n

\"\"<\/p>\n

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\"\"<\/p>\n

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\u65e0\u8bba \u6837\u54c1\u91cd\u91cf\u548c\u8d77\u59cb\u7269\u7406phi\u56e0\u5b50\uff0cDARC \u7684\u6e29\u5347 \u548c\u81ea\u70ed\u7387\u66f2\u7ebf\u90fd\u662f\u76f8\u540c\u7684\u3002<\/p>\n

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\u51c6\u786e\u7684TMR \u6d4b\u91cf\uff0c\u6839\u672c\u4e0d\u9700\u8981Phi\u6821\u6b63<\/strong><\/p>\n

\"\"<\/p>\n

DARC \u7684\u72ec\u7279\u4e4b\u5904\u5728\u4e8e\u5176\u72ec\u7279\u7684\u5dee\u5206\u7edd\u70ed\u8865\u507f\uff0c\u6d88 \u9664\u4e86\u81ea\u53d1\u70ed\u6837\u54c1\u5bf9\u73af\u5883\u548c\u6837\u54c1\u5bb9\u5668\u7684\u6240\u6709\u70ed\u91cf\u635f\u5931\uff0c \u771f\u5b9e\u5730\u8fbe\u5230\u4e86100\uff05\u7edd\u70ed\u548c\u5b9e\u6d4b\u7684TMR\u3002<\/p>\n

\u5b89\u5168\u79d1\u5b66\u5bb6\u548c\u5316\u5b66\u5de5\u827a\u5de5\u7a0b\u5e08\u4e00\u76f4\u5728\u52aa\u529b\u4f7f\u7528\u4f20\u7edf \u7684ARC\u4eea\u5668\u7814\u7a76 phi>>1 \u6761\u4ef6\u4e0b\u5bb9\u5668\u4e2d\u6d3b\u6027\u5316\u5b66\u7269 TM\u8d28\u7684 \u81ea\u53d1\u70ed\u884c\u4e3a\u3002 DARC \u73b0\u5728\u53ef\u4ee5\u5728phi\u22611\u4e0a \u7814\u7a76\u4e0e\u65f6\u95f4\u76f8\u5173\u7684\u5931\u63a7\u53cd\u5e94\uff0c\u5e76\u83b7\u5f97\u771f\u6b63\u7684\u7edd\u70ed\u5316 \u5b66\u53cd\u5e94\u6761\u4ef6\u548c\u771f\u5b9e\u7684\u53cd\u5e94\u52a8\u529b\u5b66\/\u70ed\u529b\u5b66\uff0c\u53ef\u7528\u4e8e\u76f4 \u63a5\u653e\u5927\u8ba1\u7b97\u3002<\/p>\n

\u25ce \u771f\u5b9e\u7684\u6e29\u5347\uff0c\u800c\u4f20\u7edf\u7684ARC\u65e0\u6cd5\u8fbe\u5230\u771f\u6b63\u7684\u9ad8\u6e29\u53cd\u5e94\uff1b<\/p>\n

\u25ce \u771f\u5b9e\u7684dP\/dt\uff0c\u800c\u4f20\u7edf\u7684ARC\u65e0\u51c6\u786e\u6821\u6b63\u5347\u538b\u901f\u7387\u548c\u6700\u5927\u538b\u5347\uff1b<\/p>\n

\u25ce \u5b9e\u6d4b\u7684TMR\uff0c\u800c\u5e38\u89c4ARC\u5ef6\u8fdf\u5e76\u626d\u66f2\u4e86\u53cd\u5e94\uff1b<\/p>\n

\u25ce \u96f6\u70ed\u6cc4\u9732\uff08\u5bf9\u73af\u5883\uff09\uff0c\u96f6\u70ed\u5438\u6536\uff08\u5bf9\u5bb9\u5668\uff09\uff0c\u56e0\u6b64\u96f6\u65f6\u6ede<\/p>\n

\u5728\u4f20\u7edf\u7684\u52a0\u901f\u91cf\u70ed\u4eea<\/a>\u4e2d\uff0c\u6837\u54c1\u5bb9\u5668\u7684\u70ed\u5bb9\u91cf\u5145\u5f53\u70ed\u9631\uff0c\u6291\u5236\u4e86\u6e29\u5ea6\u548c\u538b\u529b\u4e0a\u5347\u901f\u7387\u3002 ARC\u4e2d\u81ea\u53d1\u70ed\u6837\u54c1\u4ece\u672a \u8fbe\u5230\u5176\u7406\u8bba\u6e29\u5347\uff0c\u800c\u5728\u7406\u8bba\u6e29\u5347\u4e0b\u53d1\u751f\u7684\u5316\u5b66\u53cd\u5e94\u65e0\u6cd5\u4f7f\u7528\u70ed\u5bb9\u6821\u6b63\u8fdb\u884c\u6a21\u62df\u5b9e\u6d4b\u7684\uff0c\u56e0\u6b64phi\u6821\u6b63\u65b9\u6cd5\u65e0\u6cd5 \u63d0\u4f9b\u771f\u5b9e\u7684\u968f\u65f6\u95f4\u53d8\u5316\u7684\u6e29\u5ea6\u548c\u538b\u529b\u66f2\u7ebf\u3002\u5728\u4e0a\u56fe\u4e2d\uff0c\u6700\u7ec8\u7edd\u70ed\u6e29\u5347\u663e\u8457\u66f4\u9ad8\uff0c\u5e76\u4e14TMR\u503c\u663e\u8457\u77ed\u4e8e\u901a\u8fc7\u5e38 \u89c4ARC\u6d4b\u91cf\u7684\u6570\u503c\u3002<\/p>\n

\"\"<\/p>\n

\u4ea7\u54c1\u89c4\u683c<\/strong><\/p>\n

\u6e29\u5ea6\u8303\u56f4\uff1a \u5ba4\u6e29\u81f3400\u2103<\/p>\n

\u538b\u529b\u8303\u56f4\uff1a 0~5000psi<\/p>\n

\u901f\u7387\u6d4b\u91cf\u7075\u654f\u5ea6\uff1a 0.01\u81f3100 \u2103\/min HSS\uff0c0.002\u81f3100 \u2103\/min HRS<\/p>\n

\u70ed\u5316\u5b66\u6d4b\u91cf\u7075\u654f\u5ea6\uff1a \u5728\u7532\u82ef\u4e2d0.3wt\uff05DTBP<\/p>\n

\u6807\u51c6\u5bb9\u5668\uff1a \u87ba\u65cb\u76d6\u53ef\u91cd\u590d\u4f7f\u7528HastelloyC<\/p>\n

\u538b\u529b\u7b49\u7ea7\u4e3a5000psi\uff1a 10ml\uff0c<\/p>\n

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\u6700\u5c0f\u5de5\u4f5c\u5bb9\u91cf1ml<\/p>\n

\u7535\u6e90\u8981\u6c42\uff1a 120\/240 VAC\uff0c50\/60Hz \u5c3a\u5bf8\uff08\u5730\u677f\u578b\u53f7\u5404\u4e0d\u76f8\u540c\uff09\uff1a 57″H x 21″W x 27″D<\/p>\n

\u8f6f\u4ef6\uff1a WinARC\uff1aMS Windows 7,10<\/p>\n

\u53c2\u8003\u6587\u732e<\/strong><\/p>\n

e R sults of a Round-Robin with di-tertiary-butyl peroxide in various adiabatic equipment for assessment of runaway reaction hazards R.J.A.Kersten, M.N.Boers, M.M.Stork, C.Visserc https:\/\/doi.org\/10.1016\/j.jlp.2005.03.003 Performance evaluation of differential accelerating rate calorimeter for the thermal runaway reaction of di-tert-butyl peroxide Arata Kimura, Teruhito Otsuka T. J Therm Anal Calorim (2013) 113: 1585. https:\/\/doi.org\/10.1007\/s10973-013-3282-1 Influence of deteriorated solvent on induction period of Grignard reagent formation Kumasaki, M., Tanaka, K. & Otsuka, T. J Therm Anal Calorim (2015) 120: 633. https:\/\/doi.org\/10.1007\/s10973-015-4436-0<\/p>\n

 <\/p>\n

\"\"\"\"\"\"<\/p>\n

<\/div>","protected":false},"excerpt":{"rendered":"

DARC \u662f\u5168\u7403\u6700\u5148\u8fdb\u7684100%\u7edd\u70ed\u52a0\u901f \u91cf\u70ed\u4eea\u3002\u8be5\u7cfb\u7edf\u80fd\u591f\u5b9e\u6d4b\u5230\u7406\u8bba\u6e29\u5347\u548c\u771f\u5b9e \u7684\u6700\u5927\u53cd\u5e94\u901f\u7387\u65f6\u95f4\uff0c\u800c\u52ff\u9700\u8fdb\u884c\u5bb9\u5668\u70ed\u5bb9 \u6821\u6b63\u3002 \u25ce 100\uff05\u7edd\u70ed \u0394T\uff0c\u0394P\uff0cdT\/dt\uff0cdP\/d <\/p>\n","protected":false},"author":15,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":[],"categories":[1],"tags":[],"_links":{"self":[{"href":"https:\/\/www.bihec.com\/omnical\/wp-json\/wp\/v2\/posts\/1511870"}],"collection":[{"href":"https:\/\/www.bihec.com\/omnical\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.bihec.com\/omnical\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.bihec.com\/omnical\/wp-json\/wp\/v2\/users\/15"}],"replies":[{"embeddable":true,"href":"https:\/\/www.bihec.com\/omnical\/wp-json\/wp\/v2\/comments?post=1511870"}],"version-history":[{"count":1,"href":"https:\/\/www.bihec.com\/omnical\/wp-json\/wp\/v2\/posts\/1511870\/revisions"}],"predecessor-version":[{"id":1511871,"href":"https:\/\/www.bihec.com\/omnical\/wp-json\/wp\/v2\/posts\/1511870\/revisions\/1511871"}],"wp:attachment":[{"href":"https:\/\/www.bihec.com\/omnical\/wp-json\/wp\/v2\/media?parent=1511870"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.bihec.com\/omnical\/wp-json\/wp\/v2\/categories?post=1511870"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.bihec.com\/omnical\/wp-json\/wp\/v2\/tags?post=1511870"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}